20 May. 2022, our Review Article “Electrochemical Reactions Towards the Formation of Heteroatomic Bonds beyond CO2 and N2 Reduction” has been accepted by Sustainable Energy & Fuels
20 May. 2022, our Review Article “Electrochemical Reactions Towards the Formation of Heteroatomic Bonds beyond CO2 and N2 Reduction” has been accepted by Sustainable Energy & Fuels
Shivaraj B. Patil and Di-Yan Wang*
Abstract
Contemporary, electrocatalytic carbon dioxide reduction (CO2RR) and nitrogen reduction reaction (NRR) have gained enormous attention as they are recognised as green and sustainable alternatives for production of various value-added fossil fuels and ammonia (NH3), respectively. Recently, prodigious efforts have been devoted in exploring different catalysts, different products while trying to understand the reaction mechanisms by detecting intermediates using in-situ techniques and density functional theory (DFT) calculations. Currently, the research focus is shifting from obtaining C1 compounds to C2+ compounds on CO2RR and producing NH3 from nitrate (NO3ˉ). Herein, we have summarized various reaction mechanisms reported for producing different compounds including C–C, C–H, and N–H bond formation on CO2RR and NRR. Factors affecting the formation of different compounds on CO2RR is resourcefully illustrated. Furthermore, electrocatalytic formation of heteroatomic C–N bond is exemplified along with reaction mechanisms. Finally, we presented our view on challenges and opportunities in heteroatomic bond formation. This perspective may ignite robust research in developing potential electrochemical systems with dynamic catalysts beyond C–H, N–H, and C–C bond formation.
2022
| 79 | Shih-Mao Peng, Shivaraj B. Patil, Chun-Chih Chang, Shu-Ting Chang, Yi-Chia Chen, Kuan-Chang Wu, Wei-Nien Su,* Bing Joe Hwang* and Di-Yan Wang* 2022: Fast charge transfer between iodide ions and a delocalized electron system on the graphite surface for boosting hydrogen production, J. Mater. Chem. A, 2022, 10, 23982–23989. (Selected as Front Cover and 2022 HOT Journal of Materials Chemistry A article) |
| 78. | Swathi M. Gowdru, Chin-Hsuan Lin, Chun-Chih Chang,* Yi-Chia Chen,Yi-Lin Kuo, Chia-Che Chang, Shivaraj B. Patil, Chih-Wen Pao, Jeng-Lung Chen, Chang-Ru Lee, Chung-Kai Chang, Yu-Chun Chuang, Hwo-Shuenn Sheu, Chen-I Yang,* and Di-Yan Wang* 2022: Revealing Structural Transformation between Activity/stability of 2D and 3D Co-Mo Metal–organic-framework for Highly Active Oxygen Evolution Reaction, ACS Sustainable Chem. Eng., 2022, 10, 12297-12306. (Selected as Front Cover) |
| 77. | Yi-Chia Chen, Kuan-Chang Wu, Hsin-An Chen, Wen-Hui Chu, Swathi M. Gowdru, Jou-Chun Lin, Bi-Hsuan Lin, Mau-Tsu Tang, Chia-Che Chang, Ying-Huang Lai, Tsung-Rong Kuo, Cheng-Yen Wen, and Di-Yan Wang* 2022: Studies of High-Membered Two-Dimensional Ruddlesden-Popper Cs7Pb6I19 Perovskite Nanosheets via Kinetically Controlled Reactions, Mater. Horiz., 2022, 9, 2433-2442. |
| 76. | Shivaraj B. Patil and Di-Yan Wang* 2022: Electrochemical Reactions Towards the Formation of Heteroatomic Bonds beyond CO2 and N2 Reduction, Sustain. Energy Fuels, 2022, 6(14), 3283-3303. |
| 75. | Swathi M. Gowdru, Jou-Chun Lin 1, Szu-Tan Wang, Yi-Chia Chen, Kuan-Chang Wu, Cheng-Nan Jiang, Yu-Dian Chen, Shao-Sian Li,* Yuan Jay Chang, and Di-Yan Wang* 2022: Accelerated Formation of 2D Ruddlesden—Popper Perovskite Thin Films by Lewis Bases for High Efficiency Solar Cell Applications, Nanomaterials 2022, 12(11), 1816. (Invited research article without publication fee) |
| 74. | Cheng-Chieh Lin, Jia-Ying Li, Nian-Zu She, Shao-Ku Huang, Chih-Ying Huang, I-Ta Wang, Fu-Li Tsai, Chuan-Yu Wei, Ting-Yi Lee, Di-Yan Wang, Cheng-Yen Wen, Shao-Sian Li, Atsushi Yabushita, Chih-Wei Luo, Chia-Chun Chen,* and Chun-Wei Chen* 2022: Stabilized High-Membered and Phase-Pure 2D All Inorganic Ruddlesden–Popper Halide Perovskites Nanocrystals as Photocatalysts for the CO2 Reduction Reaction, Small, 2022, 18(19), 2107881. |
31 Jan. 2022, Dr. Shivaraj Patil received 2021 CSLT, Everlight Chemical Thesis Award in Green Chemistry
Dr. Shivaraj Patil received 2021 CSLT, Everlight Chemical Thesis Award in Green Chemistry
https://chemistry.org.tw/news-single.php?mTitle=department&temp_id=724
31 Jan. 2022, Prof. Wang received 2021 CSLT, Outstanding Young Chemical Researcher Award
31 Jan. 2022, Prof. Wang received 2021 CSLT, Outstanding Young Chemical Researcher Award
https://chemistry.org.tw/news-single.php?mTitle=department&temp_id=724
李昌儒
李昌儒 Chang-Ru Lee
foreverlive0740@gmail.com
2022 MS Tunghai University
Current Job: TSMC
05 Nov. 2021, Prof. Wang received Academia Sinica Early-Career Investigator Research Achievement Award in 2021
簡評：
得獎人王迪彥博士的研究著重於以地球豐富元素發展奈米結構觸媒，針對無碳排放之電催化（EC）氮還原反應（NRR），建立臨場電化學搭配光譜分析技術，結合實驗與理論深入探討NRR 機制。國際上於EC-NRR 相關研究起始於2018 年，由於其環保性質、可於大氣環境下反應、使用水性電解質及低成本催化劑等優點而於近年來備受關注。王博士針對氮氣分子在催化劑表面上之低吸附能力，以及材料結構表面對氮氣的不相容性與低穩定性所造成活性不佳之問題，提出有效的解決方法。
此外，其利用紅外光吸收了解二硫化鐵在EC-NRR 之機制及調控二硫化鉬層狀材料結構增加EC-NRR 效率均為獨創發現，具有相當的國際領先度。EC-NRR 研究不僅有其學術價值，也有實際應用性（例如氮肥產業）。王博士勇於挑戰嶄新領域，並能迅速將研究成果發表在材料化學應用於能源領域同行所認定之重要國際期刊，顯見其研究實力卓越。王博士並受Small 期刊的邀稿，發表評論文章一篇（Exploration and Investigation of Periodic Elements forElectrocatalytic Nitrogen Reduction），足證其已成為國際尚處於初始競爭階段領域之領先者，實可為年輕研究人員之表率。